50 mL of 0.1 M acetic acid is mixed with 50 mL of 0.1 M sodium acetate (the conjugate base). The Ka of acetic acid is approximately 1. 74 X 10 -5. What is the pH of the resulting solution?

Respuesta :

Answer:

4.76

Explanation:

In this case, we have to start with the buffer system:

[tex]CH_3COOH~->~CH_3COO^-~+~H^+[/tex]

We have an acid ([tex]CH_3COOH[/tex]) and a base ([tex]CH_3COO^-[/tex]). Therefore we can write the henderson-hasselbach reaction:

[tex]pH~=~pKa+Log\frac{[CH_3COO^-]}{[CH_3COOH]}[/tex]

If we want to calculate the pH, we have to calculate the pKa:

[tex]pH=-Log~Ka=4.76[/tex]

According to the problem, we have the same concentration for the acid and the base 0.1M. Therefore:

[tex][CH_3COO^-]=[CH_3COOH][/tex]

If we divide:

[tex]\frac{[CH_3COO^-]}{[CH_3COOH]}~=~1[/tex]

If we do the Log of 1:

[tex]Log~1=~zero[/tex]

So:

[tex]pH~=~pKa[/tex]

With this in mind, the pH is 4.76.

I hope it helps!