A certain reaction has an activation energy of 39.5 kJ/mol. As the temperature is increased from 25.0°C to a higher temperature, the rate constant increases by a factor of 5.90. Calculate the higher temperature (in °C).

Respuesta :

Answer:

Explanation:

We shall apply Arrhenius equation which is given below .

[tex]ln\frac{k_2}{k_1} = \frac{E_a}{R} [\frac{1}{T_1} -\frac{1}{T_2} ][/tex]

K₂ and K₁ are rate constant at temperature T₂ and T₁ , Ea is activation energy .

Putting the given values

[tex]ln\frac{5.9}{1} = \frac{39500}{8.3} [\frac{1}{298} -\frac{1}{T_2} ][/tex]

[tex].000373= [\frac{1}{298} -\frac{1}{T_2} ][/tex]

T₂ = 335.27 K

= 62.27 °C

The higher temperature is 62.27°C.

Calculating the higher temperature:

Given that the activation energy of the reaction is:

Eₐ =  39.5 kJ/mol

initial temperature T₁ = 25°C = 298K

Let the final temperature be T₂

The rate constant at temperature T₁ be K₁, and at a temperature T₂ be K₂.

According to the question: K₂/K₁ = 5.9

Now, applying the Arrhenius equation we get:

[tex]\ln\frac{K_2}{K1}=\frac{E_a}{R}[\frac{1}{T_1} -\frac{1}{T_2}]\\\\\ln(5.9)= \frac{39.5}{8.3}[\frac{1}{298} -\frac{1}{T_2}]\\\\0.000373=\frac{1}{298} -\frac{1}{T_2}[/tex]

T₂ = 335.27K

T₂ =  335.27 -273

T₂ = 62.27°C

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