From the potential energy diagram of shown, we can infer that the atoms form a bond with a bond length of 75 pm.
When atoms are far away from each other, there exists no interaction whatsoever between the atoms.
However, as the atoms draw closer to each other, the potential energy diagram begins to shift towards an energy minima as we can see from the potential energy diagram.
As the system continues to tend towards this minima, the distance between the atoms decreases. The distance at which the two atoms have the lowest energy is called the bond length.
For this system, such a bond length occurs at 75pm as we can see from the diagram.
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