The energy-releasing reaction shown is the reaction of phosphorylation of fructose-6-phosphate to fructose-1, 6-bisphosphate.
Phosphorylation simply means the biochemical process that has to do with the addition of phosphate to an organic compound.
In this case, there's a reaction with fructose-6-phosphate to fructose-1, 6-bisphosphate.
Also, the ATP molecules have three high-energy phosphate groups which are vital for the transfer of one of its phosphate groups to fructose-6-phosphate and also provide energy to carry out the reaction.
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