2 QUESTIONS: ANSWER THIS with a proper answer plz. PLZ DO NOT ANSWER JUST FOR MY BRAINLY POINTS!!!!

15. For elements 1-36, there are two exceptions to the filling order as predicted from the periodic table. Draw the atomic orbital diagrams for the two exceptions and indicate how many un​paired electrons are present.

16. The elements Si, Ga, As, Ge, Al, Cd, S, and Se are all used in the manufacture of various semiconductor devices. Write the expected electron configuration for these atoms.