Calculate the standard potential for a cell that employs the over-all cell reaction: 2Al(s) + 3 I2(s)→2 Al+3 + 6 I- From reduction potential table: Al+3 (aq) + 3e- → Al(s) -1.66 V I2(s) + 2e- → 2I- -0.54 V

Respuesta :

Answer:

Explanation:

2Al(s) + 3 I₂(s)   →    2 Al⁺³    +     6 I⁻

Aluminium is oxidised and iodine is reduced .

so cell potential = Ereduction - Eoxidation

Al⁺³ + 3e = Al          -  1.66 V

I₂ + 2 e = 2 I⁻             0.54 V

=  .54 - ( - 1.66 )

= 1.66 + .54

= 2.2  V

The overall standard cell potential for the given cell that employs the overall cell reaction is; E°_cell = 2.20 V

We are given the cell reaction;

2Al (s) + 3I₂ (s) → 2Al⁺³ + 6I⁻

We are given reduction potential as;

Al⁺³(aq) + 3e⁻ → Al(s) ;E°_red = -1.66 V

However, the standard reduction potential for the reverse of the oxidation reaction is;

Al → Al⁺³(aq) + 3e⁻ ;E°_ox = 1.66 V

We are also given;

I₂ + 2e⁻ = 2I⁻ ;E°_red = 0.54 V

To get  overall standard cell potential, we will add the cell potentials to get;

E°_cell = E°_ox + E°_red

E°_cell = 1.66 + 0.54

E°_cell = 2.20 V

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