A cation will not replace an anion in a compound because the two positively-charged ions will repel each other.
Ions are atoms or group of atoms possessing an electrical charge.
Ionic compounds are compounds which are composed of oppositely charged ions held together by strong electrostatic forces of attraction between the oppositely charged ions.
If a cation replaces an anion, the compound would have two l positive charges which will repel each other.
Therefore, a cation will not replace an anion in a compound because the two positively-charged ions will repel each other.
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