To undergo aldol condensation with itself, a carbonyl compound has to have at least one a-hydrogen. Indicate if the following have a-hydrogens. If yes, give the aldol condensation product. a. acetone, b. 3-pentanone, c. acetophenone, d. formaldehyde, e. benzophenone, d. Cyclohexanone.

Respuesta :

Yes, acetone, acetophenone and Cyclohexanone have alpha hydrogen.

The aldol condensation product are:

Acetone - Diacetone Alcohol (DAA) is produced as an intermediate product from the aldol condensation of acetone in the presence of an acid catalyst, which then dehydrates to produce Mesityl Oxide (MO).

Acetophenone - The acetophenone would produce an enolate ion under normal circumstances.

Cyclohexanone - A β -hydroxy ketone is produced when cyclohexanone goes through aldol condensation while being in the presence of a base.

What Aldol condensation?

  • In organic chemistry, an aldol condensation is a condensation reaction in which an enol or enolate ion combines with a carbonyl chemical to produce a β-hydroxyaldehyde or β-hydroxyketone.
  • Which is then dehydrated to produce a conjugated enone.

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