in(iv) sulfide, sns2, a yellow pigment, can be produced using the following reaction. snbr4(aq) 2na2s(aq)⟶4nabr(aq) sns2(s) suppose a student adds 35.2 ml of a 0.419 m solution of snbr4 to 51.1 ml of a 0.203 m solution of na2s.

Respuesta :

% yield of SnS2 = 0.337 X 100 / 0.567 = 59.44 %

% yield of SnS2 = 59.44 %

Balanced chemical reaction is

SnBr4(aq)  +  2Na2S(aq)    \rightarrow   4NaBr(aq)   +   SnS2(s)  

First calculate limiting reactant

molarity of SnBr4 = 0.418 M

volume of SnBr4 = 0.0451 L (1 ml = 0.001 L then 45.1 ml =45.1 X 0.001 = 0.0451 L)

molarity of Na2S = 0.133 M

volume of Na2S = 0.0466 M ( 1 ml = 0.001 L then 46.6 ml =46.6 X 0.001 = 0.0466 L)

no.of moles = molarity X volume of solution in liter

moles of SnBr4 = 0.418 X 0.0451 = 0.0189 mol

moles of Na2S = 0.133 X 0.0466 = 0.0062 mol

According to balanced chemical reaction 1 mole of SnBr4 react with 2 mole of Na2S molar ratio between SnBr4 to Na2S is 1:2 therefore to react with 0.0189 mole of SnBr4 required Na2S = 0.0189 X 2 / 1 = 0.0378 moles Na2S but Na2S given only 0.0062 mole therefore Na2S is limiting reactant

Limiting reactant = Na2S

According to balanced chemical reaction 2 mole of Na2S produce 1 mole of SnS2 molar ratio between Na2S to SnS2 is 2:1 therefore 0.0062 mole of Na2S produce SnS2 = 0.0062 X 1 / 2 = 0.0031 moles

Mole of SnS2 produced = 0.0031 mole

Molar mass of SnS2 = 182.81 g/mol

Gm of compound = no. of moles X molar mass

Gm of SnS2 formed = 0.0031 mol X 182.81 g/mol = 0.567 g

Gm of SnS2 formed = 0.567 g

Theoretical yield of SnS2 = 0.567 g

Actual yield of SnS2 = 0.337 g

Theoretical yield of SnS2 = 0.567 g

% yield = Actual yield X 100 / theoretical yield

Substitute the value

% yield of SnS2 = 0.337 X 100 / 0.567 = 59.44 %

% yield of SnS2 = 59.44 %

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