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Marjorie is trying to determine the identity of an unknown substance. After running tests, she determines that the substance is insoluble in CCl4 with a density of about 2.2 g/mL. Substance Density Boiling Point Solubility (in water) Solubility (in CCl4) NaCl 2.165 g/mL 1413°C soluble insoluble C10H8 1.14 g/mL 255°C insoluble soluble FeCl3 2.898 g/mL 315°C soluble insoluble SiO2 2.634 g/mL 2590°C insoluble insoluble Using the data above, which of the following substances is most likely Marjorie's unknown? A. FeCl3 B. NaCl C. SiO2 D. C10H8

Respuesta :

Marjorie's unknown substance is sodium chloride NaCl.

The substance is insoluble in CCl₄. The density of the substance is 2.2 g/mL.

Solubility:

The fact that the chemical is insoluble in CCl₄ (tetrachloromethane), as indicated in the statement, indicates that the substance is polar in nature. Only C₁₀H₈ of the choices is soluble in CCl₄ since they are both non-polar by nature and related substances dissolve similarly. C₁₀H₈ is therefore disregarded.

Density:

There are now only three possibilities left. SiO₂, FeCl₃, and NaCl. The student discovered that the material has a density of 2.20 g/ ml. This is quite similar to sodium chloride's density (i.e., 2.165 g/mL). As a result, sodium chloride is most likely the material the student is working with.

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