The Concentration of NaOH solution when NaOH solution was titrated with 25cm3 of a 0.75mol/dm3 HNO3 is 26.4 g/dm3.
Given,
Volume of HNO3 is 25cm³ = 0.025 dm³
Amount of solute in mol = concentration in mol/dm3 × volume in dm3
Amount of HNO3 = 0.75 × 0.025 = 0.018 mol
The balanced equation is: NaOH(aq) + HNO3(aq) → NaNO3(aq) + H2O(l)
So the mole ratio NaOH:HNO3 is 1:1
Therefore 0.018 mol of NaOH reacts with 0.018 mol of HNO3.
Volume of sodium hydroxide solution 27.20cm³ =
0.027 dm³.
Concentration = 0.018 / 0.027 = 0.66 mol/ dm³
Relative formula mass of NaOH= 40
Mass = relative formula mass × amount
Mass of HCl = 40 × 0.66
= 26.4
So concentration = 26.4 g/dm3
Therefore, concentration of NaOH is 26.4 g/dm3
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