15) in ketose sugars, ring formation can occur because the ketone group reacts reversibly with a hydroxyl group in an aqueous solution. this process is termed . a) hemiacetal formation b) hemicarbation c) mutarotation d) a and c only e) a and b only

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08-11-2022
Chemistry

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15) in ketose sugars, ring formation can occur because the ketone group reacts reversibly with a hydroxyl group in an aqueous solution. this process is termed . a) hemiacetal formation b) hemicarbation c) mutarotation d) a and c only e) a and b only

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AarushiAanand AarushiAanand · Answer 1 · 2022-11-12T09:23:02+01:00

in ketose sugars, ring formation can occur because the ketone group reacts reversibly with a hydroxyl group in an aqueous solution. this process is termed " mutarotation".

A shift in the homeostasis between distinct anomers inside the solution causes mutarotation, which is a variation in the specific rotation with plane-polarized light. A hemiketal and hemiacetal group is required for any molecule to exhibit mutarotation. The earliest known example of mutarotation occurred in sugar.

When the matching stereocenters likely to recidivate, the equilibrium among two anomers changes, causing the optical rotation to change. This is known as mutarotation. The interconversion of the and anomeric forms causes the rotation of cyclic sugars.

Therefore, the correct answer will be option (C)

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