Because of Avogardo Hypothesis, volumes can be used in gas phase reaction stoichiometry at constant temperature and pressure.
Avogadro's Law (also known as Avogadro's Hypothesis or Avogadro's Principle) is an experimental gas law that relates the volume of gas to the amount of gaseous matter present.
Avogadro's law states that "equal volumes of all gases at the same temperature and pressure have the same number of molecules". At constant temperature and pressure, (mol) of a gas is directly proportional.
For example, if two ideal gases, hydrogen and nitrogen, are mixed in equal amounts, they contain the same amount of molecules. This only happens if they are kept at the same pressure and temperature. This shows the ideal behavior of gases.
Let's look at this law mathematically: the overall law can be written as
V is directly proportional to n
or V = nK , K (a constant)
Amount of gas; “n” is the gaseous substance measured in moles. "k" is a constant defined for a specific pressure and temperature.
Comparing the same gas under different conditions, the law is : V₁/ n₁=V₂/ n₂
The equation shows that the number of moles of gas increases in proportion to the increase in gas volume. Therefore, the total number of atoms or molecules present in a given volume of gas is completely independent of the molar mass or size of the gas.
To learn more about Avogardo Hypothesis, refer:
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