select the single best answer. halogens are not the only atoms or groups that can be replaced by nucleophilic aromatic substitution as the following reaction shows. h512p601 what is the leaving group in this reaction? (formal charges have been intentionally omitted.) h512p60c h512p60b h512p60a

Respuesta :

NO2 is in the form of O=N+-O, As a nucleophilic leaving group it should be in form of O=N-O¯. So the correct option is first one.

What is nucleophilic aromatic substitution?

  • It is a classical reaction in which a nucleophile displaces a leaving group on an aromatic ring.
  • The presence of electron-withdrawing group increases the rate of nucleophilic aromatic substitution
  1. Nucleophilic aromatic substitution does not follow SN2 reaction mechanism, as the substitution takes place at trigonal carbon atom having sp3 hybridisation.
  2. It does not follow the SN2 reaction mechanism because of the steric hindrance of the benzene ring.
  3. Nucleophilic aromatic substitution may follow SN1 reaction mechanism in presence of an excellent leaving group.
  4. SN1 reaction would involve elimination of leaving group and formation of aryl carbocation.
  5. Generally, Nucleophilic aromatic substitution follows elimination addition or addition elimination pathway.

NO2 is in the form of O=N+-O, As a nucleophilic leaving group it should be in form of O=N-O¯. So the correct option is first one.

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