Atoms of element B from HCP lattice and those of the element A occupy 2/3 rd of tetrahedral voids. What is the formula of the compound formed by the elements A and B?

Respuesta :

In a hexagonal-close-pack (HCP) unit cell, the ratio of lattice points to octahedral holes to tetrahedral holes =  1 : 1 : 2 is AB3

let the :

Number of lattice point = 1x.

Number of octahedral points = 1x

Number of tetrahedral  points = 2x

If anions occupy the HCP lattice points and cations occupy half of the octahedral holes.

Number of anions occupying the HCP lattice points, A= 1x

Number of cations occupying the octahedral points, B =  1x

The formula of the compound will be =

If anions occupy the HCP lattice points and cations occupy all of  the octahedral and the tetrahedral holes.

Number of anions occupying the HCP lattice points, A= 1x

Number of cations occupying the octahedral points, B =  x

Number of cations occupying the tetrahedral points, B =  2x

total number of cations = x + 2x = 3x

The formula of the compound will be = AB3

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