Respuesta :
We are given the base dissociation constant, Kb, for Pyridine (C5H5N) which is 1.4x10^-9. The acid dissociation constant, Ka for the Pyridium ion or the conjugate acid of Pyridine is to be determined. We know from our chemistry classes that:
Kw = Kb * Ka
where Kw is always equal to 1x10^-14
so, to solve for Ka of Pyridium ion, substitute Kb to the equation together with Kw and solve for Ka:
1x10^-14 = 1.4x10^-9 * Ka
solve for Ka
Ka = 7.14x10^-6
Therefore, the acid dissociation constant of Pyridinium ion is 7.14x10^-6.
Kw = Kb * Ka
where Kw is always equal to 1x10^-14
so, to solve for Ka of Pyridium ion, substitute Kb to the equation together with Kw and solve for Ka:
1x10^-14 = 1.4x10^-9 * Ka
solve for Ka
Ka = 7.14x10^-6
Therefore, the acid dissociation constant of Pyridinium ion is 7.14x10^-6.
The value of an acid dissociation constant for the pyridinium ion, which is a pyridine's conjugate acid is 7.14x10⁻⁶.
How we calculate acid dissociation constant?
Acid dissociation constant will be calculated as:
Kw = Ka × Kb, where
Kw = dissociation constant of water = 10⁻¹⁴
Kb = base dissociation constant for pyridine = 1.4 × 10⁻⁹
Ka is an acid dissociation constant will be calculated as:
Ka = Kw / Kb
On putting these values on the above equation, we get:
Ka = 10⁻¹⁴ / 1.4 × 10⁻⁹
Ka = 7.14x10⁻⁶
Hence, 7.14x10⁻⁶ is the value of Ka.
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