To
determine the amount of excess reactant left, we need to first identify which
is the limiting and the excess reactant. We do as follows:
2 CH3OH(g) + 3 O2(g) = 2CO2(g) + 4 H2O(g)
24 mol CH3OH ( 3 mol O2 / 2 mol CH3OH) = 36 mol O2 needed
15 mol O2 ( 2 mol CH3OH / 3 mol O2) = 10 mol CH3OH needed
Since it is oxygen that is used up completely in the reaction, then it is the limiting reactant and the excess reactant would be the methanol. There would be 24 - 10 = 14 mol of methanol excess.