Electric potential energy is defined as Ep=Q*V where Q is the magnitude of the charge and V is the potential difference. So when a charge moves between the points that have a potential difference, it's energy changes.
In our case:
Q=2e=2*(-1.6*10^-19) C
V=75 V
Ep=(-3.2*10^-19)*75
Ep=-2.4*10^-17 J
The change in potential energy of the charge is -2.4*10^-17 J
