A gas stream entering a tray absorption tower contains 27 mol% ammonia while the rest inert gases. The tower is designed to operate at 303 K and 1.013 x 105 Pa pressure. Water consisting of 0.005 mol frac. ammonia is used as the scrubbing liquid. The total gas flow coming in is 175 kg mol/h. It is expected that the ammonia will be reduced to 2.5 mol% at the gas outlet.
a) Calculate the minimum liquid flow L 'min
b) By using graphical method, determine the number of theoretical trays required if operations is set at 1.3 times the minimum liquid flowrate. Find the values of Xn when y is set at i) 0.13 and ii) 0.3.
c) Find the values of V₁, L₁, and L. Using Kremser equation, analytically calculate the theoretical trays.

Respuesta :

Answer:

a) To calculate the minimum liquid flow rate, we can use the Murphree Efficiency equation:

\[L'_{\text{min}} = \frac{G}{K_{\text{ya}} \cdot (y_1 - y_2)}\]

Where:

- \(G\) = Total gas flow rate = 175 kg mol/h

- \(K_{\text{ya}}\) = Overall mass transfer coefficient for ammonia in the gas phase = \(1.2 \times 10^{-3}\) kmol/m²s

- \(y_1\) = Ammonia mole fraction in the inlet gas stream = 0.27

- \(y_2\) = Ammonia mole fraction in the outlet gas stream = 0.025

Plugging in the values:

\[L'_{\text{min}} = \frac{175}{1.2 \times 10^{-3} \cdot (0.27 - 0.025)}\]

\[L'_{\text{min}} \approx \frac{175}{1.2 \times 10^{-3} \cdot 0.245}\]

\[L'_{\text{min}} \approx \frac{175}{2.94 \times 10^{-4}}\]

\[L'_{\text{min}} \approx 595,238.1 \text{ kg mol/h}\]

b) To determine the number of theoretical trays required using graphical method, we need to plot the equilibrium curve and operating line on a diagram and find their intersection point.

c) To find the values of \(V_1\), \(L_1\), and \(L\), and calculate the theoretical trays using the Kremser equation, we need more information such as the reflux ratio, tray efficiency, and other design parameters.