For the reaction 〖CO〗_2 (g)+H_2 (g)⇌CO(g)+H_2 O(g) the equilibrium constant at 1000 K is 0. 53. (a) If a mixture at equilibrium in a 1 L vessel contains 0. 25 mole of CO and 0. 6 mole of H_2, how many moles of H_2 O are there in the vessel?(b) 5 moles of inert gas are added to the equilibrium mixture containing 1 mole of H_2 and 1 mole of 〖CO〗_2 in 1 L vessel. Predict the equilibrium concentration of 〖CO〗_2 and H_2 O.

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Answer:

Explanation:To solve this, we'll use the equilibrium constant expression and the given equilibrium concentrations:

(a) For the reaction: \( \text{CO}_2 (g) + \text{H}_2 (g) \rightleftharpoons \text{CO}(g) + \text{H}_2\text{O}(g) \)

The equilibrium constant expression is:

\[ K = \frac{{[\text{CO}][\text{H}_2\text{O}]}}{{[\text{CO}_2][\text{H}_2]}} \]

Given:

\[ K = 0.53 \]

\[ [\text{CO}] = 0.25 \text{ moles} \]

\[ [\text{H}_2] = 0.6 \text{ moles} \]

Let's denote the number of moles of H₂O as \( x \). Substituting the given values into the equilibrium constant expression:

\[ 0.53 = \frac{{x}}{{0.25 \times 0.6}} \]

Solving for \( x \), we get:

\[ x = 0.53 \times 0.25 \times 0.6 = 0.0795 \text{ moles} \]

So, there are 0.0795 moles of H₂O in the vessel.