0.447 moles of CO2 are released.
Calcium carbonate has a formula of CaCO3 and when heated breaks down into calcium oxide (CaO) and carbon dioxide (CO2). So the balanced reaction is
CaCO3 ==> CaO + CO2
So each mole of CaCO3 will produce 1 mole of CO2.
So let's calculate how many moles of CaCO3 we have.
44.7 g / 100.0 g/mol = 0.447 mol
And since we only have 3 significant figures, the answer already has the correct number of significant figures.