33.4C - -65C = 31.6 C, that's the degrees K you need to heat it before it vaporizes.
31.6K * 4.7J/gK * 25g = 3713 J, that's the energy to heat it to the boiling point.
23500J/mol * 25g / 17g/mol = 34559 J, that's the energy to change all the ammonia from liquid to vapor.
-12C - -33.4C = 21.4 C, that's the degrees K you need to heat it before it gets to the target temperature.
21.4K * 2.2J/gK * 25g = 1177 J, that's the energy to heat it to the target temperature.