The distribution constant for a molecule X between n-hexane and water
is 13.5. Calculate the percent of X remaining in the water phase that
was originally 0.0100 M in Z after extraction of 50.0 mL of water with
4 extractions of 10.0 mL portions of n-hexane.

Respuesta :

Answer:

X = 0.005%

Explanation:

The concentration of X remaining in the water phase can be calculated using the next equation:

[tex] [X]_{i} = (\frac{V_{aq}}{V_{or}KD + V_{aq}})^{i} \cdot [X_{0}] [/tex]

Where:

[tex]X_{i}[/tex]: is the concentration of A remaining in aqueous solution

[tex]V_{aq}[/tex]: is the volume of water

[tex]V_{or}[/tex]: is the volume of the organic solvent

KD: is the distribution constant of X between water and the organic solvent

[tex]X_{0}[/tex]: is the original concentration of X

i: is the number of extractions with the organic solvent

[tex] [X]_{i} = (\frac{50 mL}{10 mL \cdot 13.5 + 50 mL})^{4} \cdot 0.01 M = 5.34 \cdot 10^{-5} M [/tex]

The percent of X remaining in the water phase is:

[tex] [X]_{i} = 5.34 \cdot 10^{-5} \cdot 100 \% = 0.005 \% [/tex]                                

I hope it helps you!