The rate of a hypothetical reaction involving L and M is found to double when the concentration of L is doubled and to increase fourfold when the concentration of M is doubled. Write the rate law for this reaction.

Respuesta :

Answer: [tex]Rate=k[L]^1[M]^2[/tex]

Explanation:

Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

[tex]L+M\rightarrow products[/tex]

[tex]Rate=k[L]^x[M]^y[/tex]  (1)

k= rate constant

x = order with respect to L

y = order with respect to M

n =( x+y)= Total order

a)  If [L] is doubled, the reaction rate will increase by a factor of 2:

[tex]2\times Rate=k[2L]^x[M]^y[/tex]   (2)

b)  If [M] is doubled, the reaction rate will increase by a factor of 4:

[tex]4\times Rate=k[L]^x[2M]^y[/tex]   (3)

Dividing 2 by 1:

[tex]\frac{2\times Rate}{Rate}=\frac{k[2L]^x[M]^y}{k[L]^x[M]^y}[/tex]

[tex]2=2^x[/tex]

[tex]x=1[/tex]

Dividing 3 by 1

[tex]\frac{4\times Rate}{Rate}=\frac{k[L]^x[2M]^y}{k[L]^x[M]^y}[/tex]

[tex]4=2^y[/tex]

[tex]2^2=2^y[/tex]

[tex]y=2[/tex]

Thus rate law is: [tex]k[L]^1[M]^2[/tex]