Respuesta :
Answer:
3.24 × 10^5 J/mol
Explanation:
The activation energy of this reaction can be calculated using the equation:
ln(k2/k1) = Ea/R x (1/T1 - 1/T2)
Where; Ea = the activation energy (J/mol)
R = the ideal gas constant = 8.3145 J/Kmol
T1 and T2 = absolute temperatures (K)
k1 and k2 = the reaction rate constants at respective temperature
First, we need to convert the temperatures in °C to K
T(K) = T(°C) + 273.15
T1 = 325°C + 273.15
T1 = 598.15K
T2 = 407°C + 273.15
T2 = 680.15K
Since, k1= 8.58 x 10-9 L/mol, k2= 2.16 x 10-5 L/mol, R= 8.3145 J/Kmol, we can now find Ea
ln(k2/k1) = Ea/R x (1/T1 - 1/T2)
ln(2.16 x 10-5/8.58 x 10-9) = Ea/8.3145 × (1/598.15 - 1/680.15)
ln(2517.4) = Ea/8.3145 × 2.01 × 10^-4
7.831 = Ea(2.417 × 10^-5)
Ea = 3.24 × 10^5 J/mol
The activation energy is 3.24 × 10^5 J/mol
Equation:
The activation energy of this reaction can be determined using the equation:
ln(k2/k1) = Ea/R x (1/T1 - 1/T2)
Here
Ea = the activation energy (J/mol)
R = the ideal gas constant = 8.3145 J/Kmol
T1 and T2 = absolute temperatures (K)
k1 and k2 = the reaction rate constants at temperature
Now
First, we need to convert the temperatures in °C to K
So,
T(K) = T(°C) + 273.15
T1 = 325°C + 273.15
T1 = 598.15K
T2 = 407°C + 273.15
T2 = 680.15K
Since, k1= 8.58 x 10-9 L/mol, k2= 2.16 x 10-5 L/mol, R= 8.3145 J/Kmol, we can now determined Ea
So,
ln(k2/k1) = Ea/R x (1/T1 - 1/T2)
ln(2.16 x 10-5/8.58 x 10-9) = Ea/8.3145 × (1/598.15 - 1/680.15)
ln(2517.4) = Ea/8.3145 × 2.01 × 10^-4
7.831 = Ea(2.417 × 10^-5)
Ea = 3.24 × 10^5 J/mol
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