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How many milliliters of 0.200 M NaOH will be required to titrate 10.5 mL of 0.479 M H2SO4

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Ans: Volume of NaOH needed = 50.3 ml

Given:

Molarity of NaOH = 0.200 M

Molarity of H2SO4 = 0.479 M

Volume of H2SO4 = 10.5 ml

To determine:

Volume of NaOH required

Explanation:

The titration reaction can be shown as:

2NaOH + H2SO4 → Na2SO4 + 2H2O

Based on the reaction stoichiometry:

2 moles of NaOH reacts with 1 mole of H2SO4

i.e.

moles of NaOH required = 2(moles of H2SO4)

[tex]V(NaOH) * M(NaOH) = 2[V(H2SO4) * M(H2SO4)]\\\\\\V(NaOH)  = \frac{2[10.5 ml*0.479M}{0.200M} \\ = 50.3 ml[/tex]

The volume of 0.200 M NaOH needed to required to titrate 10.5 mL of 0.479 M H2SO4 is 50.3 mL

We'll begin by calculating the number of mole of H₂SO₄ in the solution. This can be obtained as follow:

Volume of H₂SO₄  = 10.5 mL = 10.5 / 1000 = 0.0105 L

Molarity of H₂SO₄ = 0.479 M

Mole of H₂SO₄ =?

Mole = Molarity × Volume

Mole of H₂SO₄ = 0.479 × 0.0105

Mole of H₂SO₄ = 5.0295×10¯³ mole

Next, we shall determine the number of mole of NaOH needed to react with 5.0295×10¯³ mole of H₂SO₄. This can be obtained as follow:

H₂SO₄ + 2NaOH —> Na₂SO₄ + 2H₂O

From the balanced equation above,

1 mole of H₂SO₄ reacted with 2 moles of NaOH.

Therefore,

5.0295×10¯³ mole of H₂SO₄ will react with = 5.0295×10¯³ × 2 = 1.0059×10¯² mole of NaOH.

Finally, we shall determine the volume of the NaOH solution needed.

Mole of NaOH = 1.0059×10¯² mole

Molarity of NaOH = 0.2 M

Volume of NaOH =?

Volume = mole / Molarity

Volume of NaOH = 1.0059×10¯² / 0.2

Volume of NaOH = 0.050295 L

Multiply by 1000 to express in mL

Volume of NaOH = 0.050295 × 1000

Volume of NaOH = 50.3 mL

Therefore, the volume of NaOH needed for the reaction is 50.3 mL

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