Respuesta :
Answer:
Entropy change = -168.3 J/mol-K
Explanation:
The entropy change is expressed as:
[tex]DeltaS = \frac{DeltaH}{T}[/tex]
For HBr, the enthalpy of condensation = -19.27 kJ/mol
Temperature T = -67 C = 273 - 67 = 206 K
Therefore, the entropy change when 1 mol of HBr condenses is:
= [tex]\frac{-19.27 kJ/mol}{206 K} =0.0935 kJ/mol-K = -93.5 J/mol-K[/tex]
Thus for the given 1.80 mol of HBr the entropy change would be:
[tex]= 1.80 mol * -93.5 J/mol- K = -168.3 J/mol-K[/tex]
The entropy change at atmospheric pressure for the condensation of 1.80 moles of HBr is;
1.8 × -93.5 J/mol K = -168.3 J/mol K
The entropy of a system is simply defined as the degree of disorderliness in the system.
Mathematically, the change in entropy (molar) for a process is calculated as follows:
- Delta S = Delta H/Temperature
The change in enthalpy, Delta H when HBr condenses, otherwise known as the Enthalpy of condensation is; -19.27 kJ/mol.
- HBr condenses at -67°C
- T = 273 - 67 = 206 K
- Delta S = -19.27/206
- Delta S = -0.0935kJ/mol K
- Delta S = -93.5 J/mol K.
The entropy change calculated above is that of 1 mole of Hydrogen bromide.
Consequently, the entropy change for 1.80 moles of HBr is;
- 1.8 × -93.5 J/mol K = -168.3 J/mol K
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