Molar mass H₂O = 18.0 g/mol
number of moles :
1.0 / 18.0 => 0.055 moles
1 mole -------------- 6.02 x 10²³ molecules
0.055 moles -------- ? molecules
molecules = 0.055 x ( 6.02 x 10²³) / 1
molecules = 3.311x10²² / 1
= 3.311 x 10²² molecules
hope this helps!